SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
| Penetrating Oil |
| Aerosol |
1.2. Relevant identified uses of the substance or mixture and uses advised against
Lubricants
1.3. Details of the supplier of the safety data sheet
| CRC Industries Europe bvba |
| Touwslagerstraat 1 |
| 9240 Zele |
| Belgium |
| Tel.: +32(0)52/45.60.11 |
| Fax.: +32(0)52/45.00.34 |
| E-mail : hse@crcind.com |
| Subsidiaries | Tel | Fax | |
| CRC Industries Finland Oy | Laurinkatu 57 A 23 B, 08100 Lohja | +358/(19)32.921 | |
| CRC Industries France | 6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex | 01.34.11.20.00 | 01.34.11.09.96 |
| CRC Industries Deutschland GmbH | Südring 9, D-76473 Iffezheim | (07229) 303 0 | (07229)30 32 66 |
| CRC INDUSTRIES IBERIA S.L.U. | GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA | 0034/921.427.546 | 0034/921.436.270 |
| CRC Industries Sweden | Laxfiskevägen 16, 433 38 Partille | 0046/31 706 84 80 | 0046/31 27 39 91 |
1.4. Emergency telephone number
CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
| Physical: | Aerosol, category 2 |
| Flammable aerosol. | |
| Pressurised container: May burst if heated. |
Classification is based on test data.
| Health: | Not classified |
Classification based on calculation method.
| Environment: | Not classified |
Classification based on calculation method.
2.2. Label elements
Labelling according to Regulation (EC) No 1272/2008
| Hazard pictogram(s): |  |
| Signal word: | Warning |
| Hazard statement(s): | H223 : Flammable aerosol. |
| H229 : Pressurised container: May burst if heated. |
| Precautionary statement(s): | P102 : Keep out of reach of children. |
| P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | |
| P211 : Do not spray on an open flame or other ignition source. | |
| P251 : Do not pierce or burn, even after use. |
| P410/412 : Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. |
| Supplemental Hazard information: | Repeated exposure may cause skin dryness or cracking. |
2.3. Other hazards
No information available
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable.
3.2. Mixtures
| Hazardous ingredient | Registration number | CAS-nr. | EC-nr | w/w % | Hazard Class and Category | Hazard statement | Notes |
| Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics | 01-2119456620-43 | - | (926-141-6) | 50-75 | Asp. Tox. 1 | H304 | B,Q |
| mineral oil (IP 346 DMSO extract < 3%) | - | - | - | 10-25 | - | - | B |
| carbon dioxide | - | 124-38-9 | 204-696-9 | 1-5 | Press. Gas | H280 | A,G |
| sulfonic acids,petroleum,sodium salts | 01-2119527859-22 | 68608-26-4 | 271-781-5 | 1-5 | Skin Irrit. 2, Eye Irrit. 2 | H315,H319 |
| Explanation notes | A : substance with Community workplace exposure limit | B : substance with national established workplace exposure limit | G : exempted from the obligation to register in accordance with art.2(7)of REACH Regulation No 1907/2006 | Q : The CAS-no is only an indicative identifier to be used outside the EU for global inventory entries. |
(* Explanation phrases : see chapter 16)
SECTION 4: First aid measures
4.1. Description of first aid measures
| Contact with eyes : | If substance has got into eyes, immediately wash out with plenty of water |
| If eye irritation persists: Get medical advice/attention. |
| Contact with skin : | Wash with plenty of soap and water. |
| If skin irritation occurs: Get medical advice/attention. |
| Inhalation : | IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| Call a POISON CENTER or doctor/physician if you feel unwell. |
| Ingestion : | If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention |
4.2. Most important symptoms and effects, both acute and delayed
| Inhalation : | Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
| Ingestion : | After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia. |
| Symptoms : sore throat, abdominal pain, nausea, vomiting |
| Skin contact : | May cause irritation. |
| Symptoms : redness and pain |
| Eye contact : | May cause irritation. |
| Symptoms : redness and pain |
4.3. Indication of any immediate medical attention and special treatment needed
| General Advice : | If you feel unwell, seek medical advice (show the label where possible |
| If symptoms persist always call a doctor |
SECTION 5: Firefighting measures
5.1. Extinguishing media
foam, carbon dioxide or dry agent
Do not use water jet extinguishing media, due to the risk of spreading fire.
5.2. Special hazards arising from the substance or mixture
| Aerosols may explode if heated above 50°C |
| Forms hazardous decomposition products |
| CO,CO2 |
5.3. Advice for firefighters
| Keep container(s) exposed to fire cool, by spraying with water |
| In case of fire, do not breathe fumes |
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
| Shut off all ignition sources |
| Ensure adequate ventilation |
| Wear suitable protective clothing and gloves. |
6.2. Environmental precautions
Do not allow to enter public sewers and watercourses
If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities
6.3. Methods and material for containment and cleaning up
Absorb spillage in suitable inert material
6.4. Reference to other sections
For further information see section 8
SECTION 7: Handling and storage
7.1. Precautions for safe handling
| Keep away from heat and sources of ignition |
| Take precautionary measures against static discharges |
| Equipment should be earthed |
| Use explosion-proof electrical/ventilating/lighting/.../equipment. |
| Use only non-sparking tools. |
| Do not breathe aerosols or vapours. |
| Ensure adequate ventilation |
| Avoid contact with skin and eyes. |
| Wash thoroughly after use |
| Wear protective gloves/protective clothing/eye protection/face protection. |
7.2. Conditions for safe storage, including any incompatibilities
| Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C. |
| Keep out of reach of children. |
7.3. Specific end use(s)
Lubricants
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Exposure limits :
| Hazardous ingredient | CAS-nr. | method | ||
| EU established exposure limits: | ||||
| carbon dioxide | 124-38-9 | TWA | 9000 mg/m3 | |
| STEL | 1800 mg/m3 | |||
| National established exposure limits, United Kingdom | ||||
| carbon dioxide | 124-38-9 | TWA | 5000 ppm | |
| STEL | 15000 ppm |
8.2. Exposure controls
| Control procedures : | Ensure adequate ventilation |
| Keep away from heat and sources of ignition | |
| Take precautionary measures against static discharges |
| Personal protection : | Take precautions to avoid contact with skin and eyes when handling the product. |
| It is good practice to wear gloves and to provide adequate ventilation whenever using the product. | |
| In all cases handle and use the product in accordance with good industrial hygiene practices. |
| inhalation : | In case of insufficient ventilation, wear suitable respiratory equipment. |
| recommended respiratory protection: | Air purifying respirator equiped with organic gas/vapor cartridge (type A) |
| hands and skin : | Depending on amount and duration of use and the risk of contact with the product the gloves manufacturer can assist you in the selection of the right glove material and breakthrough time. |
| Recommended gloves: | Nitrile |
| eyes : | Wear safety eyewear according to EN 166. |
| Environmental protection: | Avoid release to the environment. |
| Collect spillage. |
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
(for aerosols data for the product without propellant)
| Appearance : physical state : | CO2 propelled liquid. |
| colour : | Black. |
| odour : | Characteristic odor. |
| pH : | Not applicable. |
| Boiling point/range : | Not available. |
| Flash point : | > 70 °C (Closed Cup) |
| Evaporation rate : | Not available. |
| Explosion limits : upper limit : | Not available. |
| lower limit : | Not available. |
| Vapour pressure : | Not available. |
| Relative density : | 0.82 (@ 20°C). |
| Solubility in water : | Insoluble in water |
| Auto-ignition : | > 200 °C |
| Viscosity : | Not available. |
9.2. Other information
| VOC = volatile organic compounds | 590 g/l |
SECTION 10: Stability and reactivity
10.1. Reactivity
No hazardous reactions known if used for its intended purpose
10.2. Chemical stability
Stable
10.3. Possibility of hazardous reactions
No hazardous reactions known if used for its intended purpose
10.4. Conditions to avoid
Avoid overheating
10.5. Incompatible materials
Strong oxidising agent
10.6. Hazardous decomposition products
CO,CO2
SECTION 11: Toxicological information
11.1. Information on toxicological effects
| acute toxicity: | based on available data the classification criteria are not met |
| skin corrosion/irritation: | based on available data the classification criteria are not met |
| serious eye damage/irritation: | based on available data the classification criteria are not met |
| respiratory or skin sensitisation: | based on available data the classification criteria are not met |
| germ cell mutagenicity: | based on available data the classification criteria are not met |
| carcinogenicity: | based on available data the classification criteria are not met |
| toxicity for reproduction: | based on available data the classification criteria are not met |
| STOT-single exposure: | based on available data the classification criteria are not met |
| STOT repeated exposure: | based on available data the classification criteria are not met |
| aspiration hazard: | based on available data the classification criteria are not met |
Information on likely routes of exposure:
| Inhalation : | Inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
| Ingestion : | After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia. |
| Skin contact : | Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis |
| Repeated exposure may cause skin dryness or cracking. |
| Eye contact : | May cause irritation. |
Toxicological data :
| Hazardous ingredient | CAS-nr. | method | ||
| Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics | - | LD50 oral rat | > 5000 mg/kg | |
| LC50 inhal.rat | >5000 mg/kg | |||
| LD50 derm.rabit | > 5000 mg/kg |
SECTION 12: Ecological information
12.1. Toxicity
Not classified
Ecotoxicological data:
| Hazardous ingredient | CAS-nr. | method | ||
| Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics | - | IC50 algae | 1000 mg/l | |
| LC50 fish | 1000 mg/l | |||
| EC50 daphnia | 1000 mg/l |
12.2. Persistence and degradability
No experimental data available
12.3. Bioaccumulative potential
No experimental data available
12.4. Mobility in soil
Insoluble in water
12.5. Results of PBT and vPvB assessment
No information available
12.6. Endocrine disrupting properties
No experimental data available
SECTION 13: Disposal considerations
13.1. Waste treatment methods
| Product : | This material and its container must be disposed of in a safe way. |
| Do not discharge into drains or the environment, dispose to an authorised waste collection point. |
| National regulations : | Disposal should be in accordance with local, state or national legislation |
SECTION 14: Transport information
14.1. UN number
| UN-number : | 1950 |
14.2. UN proper shipping name
| Proper shipping name: | AEROSOLS |
14.3. Transport hazard class(es)
| Class: | 2.1 |
| ADR/RID - Classification code: | 5F |
14.4. Packing group
| Packing group: | Not applicable. |
14.5. Environmental hazards
| ADR/RID - Environmentally hazardous: | No |
| IMDG - Marine pollutant: | No |
| IATA/ICAO - Environmentally hazardous: | No |
14.6. Special precautions for user
| ADR/RID - Tunnelcode: | (D) |
| IMDG - Ems: | F-D, S-U |
| IATA/ICAO - PAX: | 203 |
| IATA/ICAO - CAO | 203 |
14.7. Maritime transport in bulk according to IMO instruments
Not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
The Safety Data Sheet is compiled according to the current European requirements.
| Regulation (EC) No 1907/2006 (REACH) |
| Regulation (EC) No 1272/2008 (CLP) |
| Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC. |
15.2. Chemical safety assessment
No information available
SECTION 16: Other information
| *Explanation hazard statements: | - : - |
| H280 : Contains gas under pressure; may explode if heated. | |
| H304 : May be fatal if swallowed and enters airways. | |
| H315 : Causes skin irritation. | |
| H319 : Causes serious eye irritation. |
| REVISIONS IN CHAPTRE : | 8.2. Exposure controls |
| acronyms and synonyms: | TWA = time weight average |
| STEL = short time exposure limit | |
| VOC = volatile organic compounds | |
| PBT = persistant bioaccumulative toxic | |
| vPvB = very persitant very bioaccumulative |
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.
